| Place | Performance | Athlete | Team |
| 1 | 09.92 | Q: SIMBINI - AKANI | CENTRAL GAUTENG ATHLETICS |
| 2 | 10.16 | Q: ROBERTS - RIVALDO | ATHLETICS GAUTENG NORTH |
| 3 | 10.35 | q: VAN STADEN - SHERWIN | EASTERN PROVINCE ATHLETICS |
| 4 | 10.39 | q: KARRIEM - ABDURAGHMAAN | WESTERN PROVINCE ATHLETICS |
| 5 | 10.53 | -: GABIER - LUQMAAN | WESTERN PROVINCE ATHLETICS |
| 6 | 10.54 | -: MONARENG - THEMBO | ATHLETICS GAUTENG NORTH |
| 7 | 10.57 | -: MCOSANA - SIBUSISO | ATHLETICS GAUTENG NORTH IND |
| 8 | 10.60 | -: BEZUIDENHOUT - WERNER | ATHLETICS GAUTENG NORTH IND |