| Place | Performance | Athlete | Team |
| 1 | 10.42 | Q: MATSOSO - TSEBO | CENTRAL GAUTENG ATHLETICS |
| 2 | 10.48 | Q: KUALI - DUKE | CENTRAL GAUTENG ATHLETICS |
| 3 | 10.50 | Q: PEDDY - GIANNO | WESTERN PROVINCE ATHLETICS |
| 4 | 10.66 | Q: WICKENS - GERRIT | NORTH WESTERN CAPE ATHLETICS |
| 5 | 10.71 | -: NORMAN - KYLE | EASTERN PROVINCE ATHLETICS |
| 6 | 10.81 | -: NDLOVU - VUYO | ATHLETICS CENTRAL NORTH WEST |
| 7 | 11.31 | -: VISAGIE - BRANDON | NORTH WESTERN CAPE ATHLETICS |
| 8 | 11.58 | -: DAMBUZA - AMOHELA | ATHLETICS TRANSKEI |